An experimental study on felsic rock–artificial seawater interaction: implications for hydrothermal alteration and sulfate formation in the Kuroko mining area of Japan     

Yasumasa Ogawa  Naotatsu Shikazono  Daizo Ishiyama  Hinako Sato  Toshio Mizuta 《Mineralium Deposita》2005,39(8):813-821

Experimental studies on the interactions between artificial seawater (ASW) and fresh rhyolite, perlite and weakly altered dacitic tuff containing a small amount of smectite suggest changing cation transfer during smectite-forming processes. Initially, dissolution of K from the rocks accompanies incorporation of Mg and Ca from ASW during both earlier (devitrification stage) and later smectite formation, whereas Ca incorporated with early smectite formation redissolves with progressive reaction. Barium mobility increases toward the later smectite-forming reactions. Therefore, the large amounts of barite, anhydrite and gypsum in Kuroko ore deposits are considered to have precipitated from hydrothermal solutions derived from the interaction with previously altered felsic rocks during late smectite formation, rather than by the reaction with fresh felsic rocks.Editorial handling: D. Lentz  相似文献   

Diagenetic paths in the margin of a Triassic Basin: NW zone of the Iberian Chain, Spain     

Maria Ochoa  José Arribas 《International Journal of Earth Sciences》2005,94(2):256-266

Buntsandstein deposits generated in a slowly subsiding basin on the western margin of the Iberian Chain are represented by a stratigraphic succession of fluvial deposits less than 100 m thick (conglomerates, sandstones, and shales). Diagenetic processes in sandstones can be grouped as eodiagenetic, mesodiagenetic, and telodiagenetic. Eodiagenesis can be associated with Muschelkalk, Keuper, and probably early Jurassic times. Mesodiagenesis is probably related to Jurassic times. Diagenetic chemical reactions suggest a maximum burial less than 1.5 km and low temperatures (<120°C). Patterns of porosity reduction by compaction and cementation suggest four diagenetic stages: (1) Loss of primary porosity by early mechanical compaction; (2) early cementation (K-feldspar and dolomite); (3) dissolution of cements; and (4) framework collapse by re-compaction. These stages are manifested by the presence of two types of sandstone. Type I sandstones present high intergranular volume (mean, 30%). Type II sandstones are characterized by high compactional porosity loss and exhibit low values of intergranular volume (mean, 16.9%). Type II sandstones are associated with the dissolution of cement and later re-compaction of type I sandstones. An intermediate telodiagenetic phase is deduced and related to the sharp unconformity between Lower Cretaceous sediments and the underlying sediments. This suggests that a mechanically unstable framework collapsed during the Cretaceous, generating type II sandstones. The analyzed diagenetic paths have a wide applicability on similar marginal areas of rift basins.  相似文献   

Rare earth elements and yttrium in ferromanganese deposits from the South China Sea: distribution, composition and resource considerations     

ZHONG Yi  CHEN Zhong  GONZALEZ Francisco Javier  ZHENG Xufeng  LI Gang  LUO Yun  MO Aibin  XU Antao  WANG Shuhong 《海洋学报(英文版)》2018,37(7):41-54

Ferromanganese nodules and crusts contain relatively high concentration of rare earth elements(REE) and yttrium(REY),with a growing interest in exploitation as an alternative to land-based REY resources.On the basis of comprehensive geochemical approach,the abundance and distribution of REY in the ferromanganese nodules from the South China Sea are analyzed.The results indicate that the REY contents in ferromanganese deposits show a clear geographic regularity.Total REY contents range from 69.1×10~(–6) to 2 919.4×10~(–6),with an average value of 1 459.5×10~(–6).Especially,the enrichment rate of Ce content is high,accounting for almost 60% of the total REY.This REE enrichment is controlled mainly by the sorption of ferromanganese oxides and clay minerals in the nodules and crusts.Moreover,the total REY are higher in ferromanganese deposits of hydrogenous origin than of diagenetic origin.Finally,Light REE(LREE) and heavy REE(HREE) oxides of the ferromanganese deposits in the study area can be classified into four grades: non-enriched type,weakly enriched type,enriched type,and extremely enriched type.According to the classification criteria of rare earth resources,the Xisha and Zhongsha platform-central deep basin areas show a great potential for these rare earth metals.  相似文献   

The use of microstructures for discriminating turbiditic and hemipelagic muds and mudstones          下载免费PDF全文

Yoshihiro Kase  Makoto Ito  Ken Ikehara  Shigeru Takizawa 《Sedimentology》2016,63(7):2066-2086

The microstructures of turbiditic and hemipelagic muds and mudstones were investigated using a scanning electron microscope to determine whether there are microstructural features that can differentiate turbiditic from hemipelagic sedimentary processes. Both types of muddy deposits are, in general, characterized by randomly‐oriented clay particles. However, turbiditic muds and mudstones also characteristically contain aggregates of ‘edge‐to‐face’ contacts between clay particles with long‐axis lengths of up to 30 μm. Based on observations of the clay fabric of the experimentally‐formed muds settled from previously agitated muddy fluids, these types of aggregates, hereafter referred to as ‘aggregates of clay particles’, are interpreted as having been formed by the collision of component flocs in turbulent fluids. Furthermore, some aggregates of clay particles have ‘face‐to‐face’ contacts between clay particles; this is similar to face‐to‐face aggregates characteristically developed in fluid‐mud deposits that are commonly recognized only in turbiditic mudstones, indicating the possibility of a final stage of deposition under highly‐dense conditions, such as temporary fluid muds. In conjunction with earlier proposed lithofacies‐based and ichnofacies‐based criteria, aggregates of clay particles should be useful for the differentiation of turbiditic and hemipelagic muddy deposits, particularly with limited volumes of non‐oriented samples from deep‐water successions.  相似文献   

Progradational and backstepping shoreface deposits in the Ladinian to Early Norian Snadd Formation of the Barents Sea          下载免费PDF全文

Tore G. Klausen  Alf Ryseth  William Helland‐Hansen  Helge K. Gjelberg 《Sedimentology》2016,63(4):893-916

Shoreface sandstone deposits within the Early Carnian part of the Snadd Formation of the Norwegian Barents Sea can be traced for hundreds of kilometres in the depositional strike direction and for tens of kilometres in the depositional‐dip direction. This study uses three‐dimensional seismic attribute mapping and two‐dimensional regional seismic profiles to visualize the seismic facies of these shoreface deposits and to map their internal stratigraphic architecture at a regional scale. The shoreface deposits are generally elongate but show variable width from north‐east to south‐west, which corresponds to a sediment source in the northern part of the basin and a southward decrease in longshore sediment transport. The Snadd Formation presents an example of how large‐scale progradational shoreface deposits develop. The linear nature of its shoreface deposits contrasts with more irregular, cuspate wave‐dominated deltaic shorelines that contain river outlets, and instead implies longshore drift as the main sediment source. In map view, discrete sets of linear features bounded by truncation surfaces scale directly to beach ridge sets in modern counterparts. The shoreface deposits studied here are characteristic in terms of scale and basin‐wide continuity, and offer insight into the contrast between shallow marine deposition under stable Triassic Greenhouse and fluctuating Holocene Icehouse climates. Findings presented herein are also important for hydrocarbon exploration in the Barents Sea, because they describe a hitherto poorly understood reservoir play in the Triassic interval, wherein the most prominent reservoir plays have so far been considered to be found in channelized deposits in net‐progradational delta‐plain strata that form the topsets to shelf‐edge clinoforms. The documented presence of widespread wave‐dominated shoreface deposits also has implications for how the relative importance of different sedimentary processes is considered within the basin during this period.  相似文献   

伟晶岩型锂矿成矿构造背景研究     

侯江龙  王登红 《地质论评》2016,62(S1):387-388

锂是银白色的、自然界最轻的金属,广泛应用于纺织、陶瓷、冶金、核能、新能源等领域,有“高能金属”、“21世纪的能源金属”之称。锂矿床按成因类型可分为内生和外生两种类型,内生型可具体分为花岗伟晶岩型、花岗岩型、云英岩型和岩浆热液型,外生型则包括盐湖型及地下卤水型（赵一鸣等,2004）。伟晶岩型锂矿主要开采锂辉石、透锂云母、锂云母、磷铝锂石等,是锂矿资源的重要来源。  相似文献   

鄂尔多斯盆地北部直罗组有机质特征及与铀成矿关系   总被引：2，自引：0，他引：2  

侯惠群  李言瑞  刘洪军  韩绍阳  王贵  白云生  吴迪  吴柏林 《地质学报》2016,90(12):3367-3374

本文研究了鄂尔多斯盆地典型铀矿床的有机质与铀成矿的关系。探讨了煤屑的赋存状态、煤质特征及成熟度,认为煤屑的演化程度均较低,处于低成熟阶段,有利于对铀的吸附。总体上看煤质有机质和铀矿化关系密切,铀含量与煤屑含量呈正相关关系,对铀矿物为吸附态形式。通过对该区油气包裹体的研究认为,该区存在多期次的成岩方解石胶结过程,并伴随多期次的油气包裹体发育,尤以晚期的胶结方解石矿物中存在丰富的晚期油气包裹体。研究认为晚期可能发生过油、气的运移和聚集,铀矿床的形成与赋矿砂岩中有机流体或还原性气体的充注和络合作用密切相关,因而这些丰富的有机流体和还原性气体对于铀的富集沉淀具有重要意义。  相似文献   

长江中下游成矿带陆内斑岩型矿床的成岩成矿作用   总被引：23，自引：21，他引：2  

周涛发  王世伟  袁峰  范裕  张达玉  常印佛  Noel C WHITE 《岩石学报》2016,32(2):271-288

陆内环境斑岩型矿床的发现对斑岩成矿理论的完善具有重要意义。长江中下游成矿带作为中国东部重要的陆内成矿带之一,成矿带内发育多个重要的斑岩型矿床,如铜山口Cu-Mo矿床、鸡冠嘴Cu-Au矿床、白云山Cu矿、城门山Cu-Mo矿床、武山Cu-Mo矿床、丰山洞Cu-Au矿床、丁家山Cu矿、洋鸡山Au矿、沙溪Cu-Au矿床、冬瓜山Cu-Au矿床、舒家店Cu矿床和安基山Cu矿床等。本文选取成矿带内典型的、具有代表性的斑岩型矿床,对其地质特征(地层、构造、含矿斑岩、脉体特征和围岩蚀变)、成岩成矿年代、成矿岩体的岩石化学和成岩成矿地球化学等方面的研究资料和成果进行了系统总结,讨论和试图阐明长江中下游成矿带陆内斑岩型矿床的成岩成矿作用与成矿模式。研究显示,长江中下游成矿带形成于燕山期陆内造山过程,成矿斑岩岩浆活动和成矿作用主要发生于149~105Ma之间,进一步可以分为早、中、晚三阶段:149~135Ma、133~125Ma和123~105Ma,三阶段岩浆活动和成矿作用主要发生于成矿带中的断隆区,早阶段(149~135Ma)和晚阶段(123~105Ma)多为斑岩-矽卡岩型矿化,中阶段(133~125Ma)矿化为典型的斑岩型矿化。长江中下游成矿带内斑岩型矿床的含矿斑岩为高钾钙碱性-钙碱性系列岩石,大部分具有埃达克岩的地球化学特征,可能为源自富集地幔的岩浆和加厚下地壳部分熔融的岩浆混合的产物,源自富集地幔的基性岩浆对成矿具有至关重要的作用,它的混入使得混合岩浆富水、硫和金属(Cu、Au)等。进一步通过与岩浆弧环境的斑岩型矿床对比研究发现,长江中下游成矿带斑岩型矿床一般不发育高级泥化岩帽(advanced argillic liithocaps)以及浅部的高-中硫矿化蚀变系统,含矿岩浆源区性质和成矿物质来源等与岩浆弧环境的斑岩型矿床明显不同。  相似文献   

广东厚婆坳整装勘查区锡多金属矿资源潜力分析     

武国忠  杨凤娟  王耿明 《江苏地质》2016,40(3):450-454

利用广东厚婆坳整装勘查区内的典型矿床、重点工作区、其他矿床的潜力评价成果,建立了8个定量预测模型区;然后通过综合信息分析,按热液型、斑岩型2种矿床类型在厚婆坳整装勘查区分别圈定并优选了最小预测区,进行资源量估算;最后对最小预测区进行归并整理,形成综合预测区,在此基础上提出了勘查部署建议。  相似文献   

金川铜镍矿床中新生代抬升冷却过程：来自裂变径迹的证据     

田向盛  杨婧  刘东晓  第鹏飞 《甘肃地质》2016,25(2):50-55

本文基于热年代学理论,利用锆石和磷灰石裂变径迹测年数据及对磷灰石热史的模拟,分析探讨金川铜镍矿床在中新生代的抬升冷却过程,认为金川超基性岩体自中生代以来一直处于持续的冷却抬升阶段,且在中侏罗世和晚白垩世早期经历了两期快速的抬升冷却事件,推断此事件与青藏高原后期活动时间相对应,证明金川岩体受到该事件的远程效应波及,致使该矿床遭受了一定的改造。  相似文献